Abstract

Abstract Divalent europium (Eu2+) complexes with polymer ligands containing 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane ([2.2.2] cryptand) and 4,7,13,16,21-pentaoxa-1,10-diazabicyclo[8.8.5]tricosane ([2.2.1] cryptand) have been synthesized. The complexes emitted ca. 450 nm luminescence by ultra violet excitation. A Eu2+-[2.2.2] cryptate-attaching polymer had high luminescence efficiency and its maximum relative emission intensity was ca. 19% with respect to an NBS standard, CaWO4:Pb.

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