Abstract
Broad-band luminescence with maximum at 3.35eV has been revealed from new luminescence material CsTaF6 under VUV excitation. This luminescence was interpreted as emission of molecular type self-trapped excitons localized at the [Ta F 6]ˉ complexes. The energy of effective vibrational mode responsible for exciton-lattice coupling was determined to be equal to 45 meV (363 cm-1), which does not correspond to the energy of breathing mode of [Ta F 6]ˉ complex vibrations. The observed luminescence possesses thermal quenching with activation energy ∼58 meV.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
