Abstract
Binding interactions of ruthenium(II) photosensitizers with non-ionic surfactants were studied using an emission intensity method. A quantitative model that permits evaluation of binding constants and critical micelle concentrations is given for the binding. Binding constants obtained by the intensity method agree within experimental error with results obtained by an analogous lifetime method. The intensity method uses more readily available instrumentation, is more rapid and lends itself better to weak binding systems than the lifetime method.
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