Abstract
The semiempirical method for calculation of the dipole moment functions for NO and CO molecules as a piecewise-continuous ones has been developed. The dipole moment functions found exhibit physically correct asymptotic behaviour at small and large internuclear separations and agree with the dipole moment functions near the nuclear equilibrium position of the molecule. In the framework of the approach the multipole and exhange interactions have been considered to improve the dipole moment function under large internuclear distances including the range of small overlapping of the electronic shells for the interacting atoms.
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