Abstract
The inhibition efficiency and adsorption characteristics of alkaloids, flavonoids and tannins extracts of Mangifera indica leaves in controlling corrosion of Zinc sheet in 5 M hydrogentetraoxosulphate (VI) acid solution has been evaluated by gasometric method. The formulation consisting of 2 g/L of extract offers 96.2%, 85.3% and 70.6% inhibition efficiencies (alkaloids, flavonoids and tannins respectively) at 300C to Zinc metal immersed in 5 M hydrogentetraoxosulphate (VI) acid solution. Judging from the trend in inhibition efficiency against temperature, it can be deduced that the adsorption process was physisoption being that corrosion rate increased while inhibition efficiency decreased with temperature. Adsorption mechanism followed the Langmuir adsorption isotherm being that the correlation coefficient was found to be approximately unity i.e. 0.9237. © JASEM
Highlights
To be realistic, corrosion can only be reduced significantly or delayed to a reasonable extent
This indicates that the plant extracts mitigate the corrosion of Zinc in 5 M H2SO4 solutions and that the extent of corrosion inhibition depends on the amount of the extract present (Xiaoyuan and Singh, 2010)
It is observed that inhibition efficiency increases in the order AEMIL > FEMIL > TEMIL .This suggests that alkaloid extract of Mangifera indica L are adsorbed more on the metal surface thereby protecting metal from the action of corrodent
Summary
Corrosion can only be reduced significantly or delayed to a reasonable extent. Controlling of the pH or ion concentration of the solution or controlling the metal solution interface had a number of ways to achieve the reduction in the rate of corrosion over the years. This is achieved through the addition of small quantity of chemicals called inhibitors, that either encourage film formation or form a barrier like layer on the metal surface and by so doing stop or slow down the rate of metal decomposition (Obot et al, 2011). Corrosion inhibitors are chemicals either synthetic or natural which when added in small quantity to an environment, decrease the rate of attack by the environment on metals (Lebrini et al, 2011)
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