Abstract
AbstractSingle crystal X‐ray diffraction analyses of LSn(OCH2CH2)2NR [1, R = Me, L = lone pair; 2, R = Me, L = W(CO)5; 3, R = t‐Bu, L = W(CO)5] reveal these compounds to be dimeric and cis‐configurated. The dimerization is realized by intramolecular O→Sn interactions to give four‐membered Sn2O2‐rings. In addition, there are intramolecular N→Sn interactions ranging in between 2.356(5) (2) and 2.549(4) Å (3).
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