Abstract

The paper reports on a low-temperature (8 K) time-resolved spectroscopic study of excitonic states and radiative relaxation of electronic excitations in undoped APb2X5 crystals (A ≡ K, Rb; X ≡ Cl, Br) performed under selective photoexcitation by synchrotron radiation. The study has revealed a variety of channels of radiative relaxation of intrinsic electronic excitations, which should be primarily assigned to specific features of the electronic structure of the crystal.

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