Low-temperature heat capacities and thermodynamic properties of ethylenediammonium tetrachlorozincate chloride (C 2H 10N 2) 2(ZnCl 4)Cl 2

Abstract

The ethylenediammonium tetrachlorozincate chloride (C 2H 10N 2) 2(ZnCl 4)Cl 2 was synthesized. Chemical analysis, elemental analysis, and X-ray crystallography were applied to characterize the composition and crystal structure of the complex. Low-temperature heat capacities of the compound were measured by a precision automatic adiabatic calorimeter over the temperature range from T = 77–377 K. A polynomial equation of heat capacities as a function of the reduced temperature was fitted by a least square method. Based on the polynomial equation, the smoothed heat capacities and thermodynamic functions of the title compound relative to the standard reference temperature 298.15 K were calculated at intervals of 5 K. A thermochemical cycle was designed and the enthalpy change of the solid phase reaction of ethylenediamine dihydrochloride with zinc chloride was determined to be Δ r H m ° = − ( 17.9 ± 0.6 ) kJ mo l − 1 by an isoperibol solution-reaction calorimeter. Finally, the standard molar enthalpy of formation of the title compound was derived to be Δ f H m ° [ ( C 2 H 10 N 2 ) 2 ( ZnC l 4 ) C l 2 , s ] = − ( 1514.4 ± 2.7 ) kJ mo l − 1 in accordance with Hess law.