Abstract
The ion-pair formation and electrochromatographic behavior of 22 anions are studied on plain and titanium (IV) tungstate impregnated papers using 0.1 N and 1 N solutions of NaNO3, Mg(NO3)2, Al(NO3)3, Cr(NO3)3, and Co(NO3)2 as background electrolytes. The effect of ion-pair formation on the migration of anions is studied. In general, the mechanism of migration is explained in terms of adsorption, precipitation, and complex formation. A number of binary and ternary separations are achieved. In Mg(NO3)2 media, the migration is correlated with the solubility of their magnesium salts for SO3(2-), C2O4(2-), SeO3(2-), AsO4(3-), and Fe(CN)6(4-).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.