Abstract

We have measured the lattice parameters in the system SmH 1.99+ x for 0 ⩽ x ⩽ 0.6 for the first time between liquid nitrogen and room temperature and determined the existence region for the pure β-phase between 1.99(1) and 2.45(3) at H/at Sm. Anomalies in the thermal expansion coefficients are observed near 230 and 190 K, respectively for x = 0.26 and x = 0.45, which are tentatively attributed to ordering of hydrogen atoms in the octahedral sublattice.

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