Abstract

Abstract We found some novel synthesis routes for alkali-metal molybdenum bronzes. The synthesis techniques are composed of simple hydrothermal treatments of mixed-valence compounds (or mixtures) with ACl or ACl + AOH aqueous solutions (A = alkali metal). Using these routes blue bronze (K0.30MoO3) and red bronze (K0.33MoO3) were obtained from hydrogen molybdenum bronze HxMoO3 or HxMoO3 + MoO3 even at 410 K.

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