Abstract
This paper presents synthesis of calcium cobaltites of the nominal composition of Ca3Co4O9 prepared by the solid state reaction. The reaction between CaCO3 and Co3O4 was investigated at 700–900 °C during 20 h and at 800 °C during 2–30 h. Mass changes, phase composition and Co+3, Co+4 content were examined. Stability of the calcined specimens was tested by DTA/TG. It was found that two phases: Ca3Co4O9 and Ca3Co2O6 were present as a result of calcinations above 800 °C. On the other hand, the temperature of 750 °C was too low for calcium cobaltites to be synthesized. Mono-phase material with Ca3Co4O9 phase was obtained after calcinations at 800 °C but non-stoichiometry of the compound and its relation to the calcinations time were found. Once synthesized, the compound was stable up to 900 °C.
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