Low-Temperature Synthesis and Mechanical Properties of SiC Porous Granules from Activated Charcoal with a Na Flux

Abstract

SiC porous granules were synthesized from activated granular charcoal and Si powder at 973 K by using a Na flux. The SiC granules maintained the shape of the charcoal with a dimension of about 5 mm in diameter and 7–10 mm in length. X-ray diffraction showed the structure of the formed SiC to be cubic � -type. Agglomerates of a few dozen nm of SiC grains and an electron diffraction ring pattern of � -SiC were observed with a transmission electron microscope. A micropore size distribution of < 4 nm and mesopores in the range of 20–40 nm were shown by a nitrogen adsorption technique. The SiC granules had a specific surface area of 3:4 � 1:0 m 2 /g and a pore volume of 0:006 � 0:002 cm 3 /g. The fracture stress of the SiC porous granules was evaluated to be 47 MPa by a compressive test at room temperature. The Vickers hardness of the granule surface was 13:1 � 1:0 GPa. [doi:10.2320/matertrans.MAW200859]