Abstract

Low temperature calorimetric measurements were made on some h.c.p. Mo-Ru and Mo-Rh alloys. By plotting the electronic specific heat coefficient (γ) as a function of the average number of valence electrons to atom ratio ( e a ), a common curve was obtained to approximate the 4 d band shape in the e a range of 7.0–8.4. This curve has a minimum at e/ a $ ̃ 8.1. The variation of Debye temperature with e a is inversely correlated to that of γ. Superconducting properties of some of the alloys are discussed.

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