Low-Temperature Sintering of SiC Ceramics using a Mixture of Preceramic Precursor and Metal Nanoparticles

Abstract

Polymer infiltration and pyrolysis (PIP) has a limitation in increasing the relative density of SiC ceramics above 90%. This is due to the blockage of open pore channels. In this study, a new process that incorporates Ni and graphite nanoparticles into SiC preceramic precursor is examined. Ni nanoparticles react with the SiC precursor to form low melting point nickel silicide phases which infiltrate into pores of the bulk without a blockage problem. In later infiltration cycles, graphite nanoparticles are added to convert the nickel silicide to nickel carbide and silicon carbide, which may prevent the deterioration of mechanical strength at high temperature. The relative density of SiC ceramics in this study increases to 92% and above, which is higher than that of SiC ceramics prepared by the traditional PIP. The results of this study show a pathway to process high density SiC ceramics at relatively low sintering temperatures.