Abstract
Physically crosslinked low-temperature elastomers were prepared based on linear polydimethylsiloxane (PDMS) elastic chains terminated on both ends with mesogenic building blocks (LC) of azobenzene type. They are generally (and also structurally) highly different from the well-studied LC polymer networks (light-sensitive actuators). The LC units also make up only a small volume fraction in our materials and they do not generate elastic energy upon irradiation, but they act as physical crosslinkers with thermotropic properties. Our elastomers lack permanent chemical crosslinks—their structure is fully linear. The aggregation of the relatively rare, small, and spatially separated terminal LC units nevertheless proved to be a considerably strong crosslinking mechanism. The most attractive product displays a rubber plateau extending over 100 °C, melts near 8 °C, and is soluble in organic solvents. The self-assembly (via LC aggregation) of the copolymer molecules leads to a distinctly lamellar structure indicated by X-ray diffraction (XRD). This structure persists also in melt (polarized light microscopy, XRD), where 1–2 thermotropic transitions occur. The interesting effects of the properties of this lamellar structure on viscoelastic and rheological properties in the rubbery and in the melt state are discussed in a follow-up paper (“Part II”). The copolymers might be of interest as passive smart materials, especially as temperature-controlled elastic/viscoelastic mechanical coupling. Our study focuses on the comparison of physical properties and structure–property relationships in three systems with elastic PDMS segments of different length (8.6, 16.3, and 64.4 repeat units).
Highlights
This work is dedicated to low-temperature reversible elastomers which melt somewhat below room temperature and which are based on linear polydimethylsiloxane (PDMS) of different chainPolymers 2020, 12, 2476; doi:10.3390/polym12112476 www.mdpi.com/journal/polymersPolymers 2020, 12, 2476 lengths, terminated with liquid crystalline (LC) units in the α- and ω- position
Several copolymers consisting of polydimethylsiloxane (PDMS) of different chain length, α,ω-terminated with mesogenic units of azobenzene-type (“BAFKU”), were synthesized and studied as potential passive smart materials
The structure of the constituent components of the prepared low-temperature reversible rubbers is shown in Scheme 2; they were chosen in order to combine properties of PDMS, such as polymer backbone flexibility and a low glass transition temperature (Tg ), with the crystallization tendency of the liquid crystalline BAFKU units, which had to act as thermotropic physical crosslinks, via BAFKU–BAFKU aggregation, as shown in Scheme 1
Summary
This work is dedicated to low-temperature reversible elastomers which melt somewhat below room temperature and which are based on linear polydimethylsiloxane (PDMS) of different chain. The relatively rarely studied main-chain polysiloxane LCPs, to which the materials studied in this work belong, were investigated mainly for their thermotropic phase behavior (polyester-co-PDMS systems) [12,13,14,15], for their thermomechanical properties [15], as thermosensitive actuators (mechanism via smectic ↔ isotropic transition of the polyester LC units) [16], or as photoresponsive optical material (azo units’ cis/trans isomerization) [17]. The LC building blocks were expected to play a somewhat similar role (non-covalent crosslinker) like the inorganic POSS units studied in the authors’ early work Due to their specific properties, the LC units could cause interesting thermotropic behavior of the physical crosslinks in the studied materials. Is dedicated to the study of the complex viscoelastic and rheological properties of the copolymers in the molten as well as in the rubbery state
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
