Abstract

Abstract— Corrected emission spectra and fluorescence lifetimes of polycytidylic acid in ethylene glycol: water glass at low temperatures are reported. Luminescence properties observed exhibit a strong dependence on pH and temperature. At neutral pH a vibronic structure of a blue part of the fluorescence spectrum is revealed when temperature is changed from 77 to 10 K, confirming that a monomer component of fluorescence is present. There is also a strong difference in decay of a red‐shifted excimer fluorescence at 10 K at pH 7 and pH 3.9, reflecting a different protonation of cytosine residues and different conformations of polynucleotides in such conditions.

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