Low Temperature Kinetics of the First Steps of Water Cluster Formation.

Abstract

We present a combined experimental and theoretical low temperature kinetic study of water cluster formation. Water cluster growth takes place in low temperature (23-69K) supersonic flows. The observed kinetics of formation of water clusters are reproduced with a kinetic model based on theoretical predictions for the first steps of clusterization. The temperature- and pressure-dependent association and dissociation rate coefficients are predicted with an abinitio transition state theory based master equation approach over a wide range of temperatures (20-100K) and pressures (10^{-6}-10 bar).