Abstract

Using laser flash photolysis, the photoisomerization and cis-trans equilibrium relaxation of 4-amino azobenzene and 4-dimethylamino azobenzene was studied. At low temperature, cis conformers on photoexcitation produced trans cont'ormers along with a fast-decaying intermediate absorbing in 450–490 nm region. These short-lived intermediates were assigned as their zwitterions.

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