Low temperature charge transport and microwave absorption of carbon coated iron nanoparticles–polymer composite films

Abstract

In this paper, the low temperature electrical conductivity and microwave absorption properties of carbon coated iron nanoparticles–polyvinyl chloride composite films are investigated for different filler fractions. The filler particles are prepared by the pyrolysis of ferrocene at 980°C and embedded in polyvinyl chloride matrix. The high resolution transmission electron micrographs of the filler material have shown a 5nm thin layer graphitic carbon covering over iron particles. The room temperature electrical conductivity of the composite film changes by 10 orders of magnitude with the increase of filler concentration. A percolation threshold of 2.2 and an electromagnetic interference shielding efficiency (EMI SE) of ∼18.6dB in 26.5–40GHz range are observed for 50wt% loading. The charge transport follows three dimensional variable range hopping conduction.