Abstract
We report here a detailed RAIRS study of carbon monoxide adsorbed on the Cu(1 1 1) surface at substrate temperatures of 15–20 K. Surface diffusion in this temperature regime is thermally limited; this results in the formation of a different, more disordered surface structure than those grown at higher temperatures. Both monolayer and multilayer physisorption is observed, and these layers are found to affect the underlying chemisorbed layer.
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