Abstract

Abstract Low-symmetrical phthalocyanines (Pcs) 2-5 prepared by mixed condensation of tetraphenylphthalonitrile and 4-phenylthiophthalonitrile in the presence of a copper salt, show spectroscopic, electrochemical, and molecular model indications which suggest varying degrees of non-planar distortions of the Pc plane and unexpected S1 state degeneracy.

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