Low potential electrochemical polymerization of diphenyl ether and characterization of its polymers

Abstract

High-quality poly(diphenyl ether) (PDPE) films with electrical conductivity of 4.4 X 10 -1 S cm -1 were synthesized electrochemically by direct anodic oxidation of diphenyl ether (DPE) in boron trifluoride diethyl etherate (BFEE) containing 5% concentrated sulfuric acid (SA) (by volume). The oxidation potential onset of DPE in pure BFEE was measured to be only 1.37 V versus a saturated calomel electrode (SCE), which was much lower than that determined in acetonitrile +0.1 mol L -1 tetrabutylammonium tetrafluoroborate (1.98 V vs. SCE). The addition of SA to BFEE can further decrease the oxidation potential onset of the monomer to 1.18 V versus SCE in the mixed electrolyte of BFEE + 5% SA. PDPE films obtained from this medium showed good redox activity and stability even in concentrated SA. Dedoped PDPE films were partly soluble in the strong polar organic solvent dimethyl sulfoxide. Fluorescent spectral studies indicated that soluble PDPE was a good blue-light emitter with a quantum yield of 0.30. Infrared spectroscopy and quantum chemistry and C 4 .