Low-energy electron inelastic mean free path for monolayer graphene

Abstract

The electron inelastic mean free path (IMFP) is an important quantity for electron spectroscopy and microscopy techniques. At present, there are very few data of IMFPs for two-dimensional (2D) materials. Here, we determine the IMFP at energies below 100 eV for monolayer graphene both experimentally and theoretically. The experimental determination is based on a data-driven spectral analysis technique, including the virtual substrate method and the reverse Monte Carlo method. The theoretical determination is performed within the dielectric formalism, using the energy-loss function calculated in the time-dependent density functional theory. The experimental and theoretical results show that the IMFP for monolayer graphene is almost constant (about 1 nm) in the energy range of 6–100 eV. This study suggests a general and reliable approach to determine low-energy IMFPs for 2D materials.