Abstract
By matching 1/m^2 divergences in finite-volume two-point correlation functions of the scalar or pseudoscalar densities with those obtained in chiral perturbation theory, we derive a relation between the Dirac operator zero-mode eigenfunctions at fixed non-trivial topology and the low-energy constants of QCD. We investigate the feasibility of using this relation to extract the pion decay constant, by computing the zero-mode correlation functions on the lattice in the quenched approximation and comparing them with the corresponding expressions in quenched chiral perturbation theory.
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