Low-dimensional materials for photovoltaic application

Abstract

The photovoltaic (PV) market is currently dominated by silicon based solar cells. However technological diversification is essential to promote competition, which is the driving force for technological growth. Historically, the choice of PV materials has been limited to the three-dimensional (3D) compounds with a high crystal symmetry and direct band gap. However, to meet the strict demands for sustainable PV applications, material space has been expanded beyond 3D compounds. In this perspective we discuss the potential of low-dimensional materials (2D, 1D) for application in PVs. We present unique features of low-dimensional materials in context of their suitability in the solar cells. The band gap, absorption, carrier dynamics, mobility, defects, surface states and growth kinetics are discussed and compared to 3D counterparts, providing a comprehensive view of prospects of low-dimensional materials. Structural dimensionality leads to a highly anisotropic carrier transport, complex defect chemistry and peculiar growth dynamics. By providing fundamental insights into these challenges we aim to deepen the understanding of low-dimensional materials and expand the scope of their application. Finally, we discuss the current research status and development trend of solar cell devices made of low-dimensional materials.