Low cost Na2FeSiO4/H–N-doped hard carbon nanosphere hybrid cathodes for high energy and power sodium-ion supercapacitors

Abstract

Na 2 FeSiO 4 (NFS)/H–N-doped hard carbon nanospheres (HN-HCNSs) hybrid cathodes have been synthesized by using ferrous gluconate as template and carbon source via sol-gel method for the first time. In the structure of this hybrid cathode, the ultrathin NFS nanosheets are uniformly anchored in the mesoporous network structure of HN-HCNSs coating, forming the fast conductive transport pathways for electrons and Na + -ions. The NFS/HN-HCNSs hybrid cathode shows a hybrid energy storage mechanism with high initial discharge capacity of 218.4 mAh g −1 at 0.1 C and in the voltage range of 1.2–4.6 V versus Na/Na + . It also shows excellent long-term cycling stability (the capacity retention rates of 73.8% at 1 C after the 3300 cycles and 56.8% at 5 C after the 750 cycles in the voltage range of 1.5–4.6 V). Moreover, the unique mesoporous carbon-coated structural features endow the hybrid cathode with a maximum energy density of 331.99 W h kg −1 and a maximum power density of 2431.87 W kg −1 within working voltage range of 1.5–4.6 V. • Na 2 FeSiO 4 /H–N-doped mesoporous hard carbon nanosphere hybrid cathodes was synthesized. • Ferrous gluconate template controlled the formation of mesoporous carbon-coated structure. • This structure gives a remarkable synergic effect of Na-ion battery-supercapacitor. • This hybrid electrode delivers high energy and power densities.