Abstract

Fatty acid methyl esters (FAMEs) are sustainable biofuel that can alleviate high oil costs and environmental impacts of petroleum-based fuel. A modified 1200 W high-efficiency food blender was employed for continuous transesterification of various refined vegetable oils and waste cooking oil (WCO) using sodium hydroxide as a homogeneous catalyst. The following factors have been investigated on their effects on FAME yield: baffles, reaction volume, total reactant flow rate, methanol-oil molar ratio, catalyst concentration and reaction temperature. Results indicated that the optimal conditions were: 2000 mL reaction volume, 50 mL/min total flow rate, 1% and 1.25% catalyst concentration for refined palm oil and WCO, respectively, 6:1 methanol-to-oil molar ratio and 62–63 °C, obtaining yield efficiency over 96.5% FAME yield of 21.14 × 10–4 g/J (for palm oil) and 19.39 × 10–4 g/J (for WCO). All the properties of produced FAMEs meet the EN 14214 and ASTM D6751 standards. The modified household food blender could be a practical and low-cost alternative biodiesel production apparatus for continuous biodiesel production for small communities in remote areas.

Highlights

  • Fatty acid methyl esters (FAMEs) are sustainable biofuel that can alleviate high oil costs and environmental impacts of petroleum-based fuel

  • Most commercial-level biodiesel production processes commonly use vegetable oil reacting with alcohol, mostly methanol, through a chemical process called transesterification to produce fatty acid methyl esters (FAMEs) and glycerol together with conventional homogeneous base or acid c­ atalysts[9,10]

  • FAME production based on refined palm oil

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Summary

Introduction

Fatty acid methyl esters (FAMEs) are sustainable biofuel that can alleviate high oil costs and environmental impacts of petroleum-based fuel. The effect of reaction volume (1000, 1500, 2000, 2500 and 3000 mL) was first studied, followed by the effect of reactant total flow rate (25, 50 and 75 mL/min) on FAME yield with the conditions of NaOH loading of 1 wt%, methanol to oil molar ratio of 6:1 and reaction temperature of 62–63 °C.

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