Abstract
A new method is presented for separation of lithium from silicate rocks and high precision MC-ICPMS analysis. A relatively small (3.57 meq) resin volume is able to separate lithium from all silicate rocks in a single step using only 16 ml of nitric acid mixed with methanol. Some advantages of the method are high sample throughput, low blanks and elution parameters that are insensitive to lithology. Elution schemes are presented for a range of igneous rocks and minerals. δ 7Li values for standards from the U.S. Geological Survey (USGS) for BCR-1, BHVO-2 and AGV-2 are 2.4‰, 4.6‰ and 7.9‰, respectively. Reference materials from the Geological Survey of Japan (GSJ) JB-2 and JR-2 give δ 7Li values of 4.7‰ and 3.8‰, respectively. The data for most reference rocks reproduce to within better than 0.5‰. This column method can also be used for the direct separation of high-field-strength elements (Ti, Zr, Hf, Nb, Ta) from silicate rocks.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
