Low-Al and high-Al trondhjemites in the Huai’an Complex, North China Craton: Geochemistry, zircon U–Pb and Hf isotopes, and implications for Neoarchean crustal growth and remelting

Abstract

Voluminous tonalite–trondhjemite–granodiorite (TTG) magmas were emplaced in the Huai’an Complex of North China Craton (NCC) during the Neoarchean. Here we present the geochemical characteristics of these rocks and identify low-Al (LAl) and high-Al (HAl) types of trondhjemites within the TTG suite. The LAl group displays high silica (SiO2=77–80wt.%), and low Al2O3 contents (11.06–11.89wt.%), a strongly peraluminous (A/CNK=1.16 and 1.19) composition and enrichment in HREE (LaN/YbN=4 and 5, GdN/YbN=0.35 and 0.9). Their low Rb (13 and 28ppm), Th (0.3 and 7.0ppm), relatively high Na2O/K2O values (3.6 and 4.1) and MgO (0.63 and 0.68wt.%) with moderately high Mg# (36 and 53), suggest crystallization from a primitive source. The HAl group is characterized by relatively low SiO2 (67.22–71.57wt.%) and high Al2O3 contents (16.35–16.41wt.%) with trace element contents and distribution patterns closely comparable to those of Archean high-Al TTGs. Our geochemical data do not favor a direct genetic link between the LAl and HAl trondhjemite groups. The zircon U–Pb data reveal that the LAl and HAl groups represent coeval intrusions at ca. 2.55–2.5Ga. In situ analysis of Hf isotopes in the zircons (εHf=+5.6 to +10, and TDM=2462–2595Ma), together with the geochemical features of the low-Al trondhjemites suggest that they were generated under relatively low pressure (<8kbar), through low degree partial melting of a newly accreted amphibolitic crust. Taking into consideration the contemporaneous (2.55–2.50Ga) high-Al TTGs widely exposed in the Huai’an Complex, we suggest that the low-Al trondhjemites were formed by intraplating of mantle-derived magmas, and the coeval high-Al TTGs were produced by partial melting of a thickened lower crust, triggered by underplating. Our study attests to a major episode of Neoarchean crustal growth in the NCC, and remelting induced by underplating and intraplating of mantle-derived magmas.