Abstract

The Lorentz friction for surface plasmons in metallic nanospheres has been analyzed versus nanoparticle size upon random-phase approximation quasiclassical method. An accurate inclusion of the Lorentz friction to the plasmon damping has been performed. Total attenuation of surface plasmons in a metallic nanosphere has been calculated and minimized with respect to the radius of the nanosphere. Experimentally measured anomalous red-shift of plasmon resonance frequency, increasing with the metallic particle radius growth, especially pronounced for a large size limit, was explained in agreement with the experimental data for Au nanospheres of radii 10–75 nm (the measured quantity being the extinction of the light trans-passing through the water colloidal solution of metallic nanospheres with various radii). A very good agreement of the measured data and the theory with properly included Lorentz friction has been achieved.

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