Abstract
The equation of state of a hard sphere fluid at high density should exhibit a simple pole at the random close packing limit. Here we show that trying to obtain a compact semi-empirical equation of state simultaneously compatible with that asymptotic behaviour and with the known virial coefficients raises an analytical difficulty which can be solved if a glassy transition occurs in the disordered metastable phase at a density intermediate between the freezing point and the random close packing limit. The comparison of the estimated value for the transition point with earlier estimations suggests a more subtle situation.
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More From: Physica A: Statistical Mechanics and its Applications
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