Abstract
A new tri-cyanometalate building block for heterometallic complexes, [PPh 4] 2[Fe II(Tpms)(CN) 3] ( 2) (PPh 4 = tetraphenylphosphonium; Tpms = tris(pyrazolyl) methanesulfonate), has been prepared. Using it as a building block, a one-dimensional chain compound, {[Fe II(Tpms)(CN) 3][Mn II(H 2O) 2( DMF) 2]} · DMF ( 3), has been synthesized and structurally characterized. The magnetic properties of 3 correspond to a ferromagnetic chain with weak long-range superexchanged magnetic interaction between the high-spin manganese(II) ions.
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