Long-Term Stabilization/Solidification of Arsenic-Contaminated Sludge by a Blast Furnace Slag-Based Cementitious Material: Functions of CaO and NaCl.

Abstract

Arsenic is a kind of element widely distributed in the environment that may pose a threat to the ecological environment and human health, while effective remediation and sustainable utilization of arsenic-containing sludge is a challenge. Based on stabilization/solidification blast furnace slag-based cementitious materials (BCMs), this study innovatively proposes to improve the arsenic (As) solidification efficiency and long-term stability by using the activation mode of CaO and NaCl. The effects of different factors on the properties of the BCM were measured by unconfined compressive strength (UCS) tests, X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy. The long-term stability and safety of the BCM were verified by leaching toxicity and improved three stage continuous extraction method (BCR) tests. Experimental results show that the addition of CaO provides conditions for the formation of ettringite (AFt), thus promoting the crystal growth of AFt. The addition of NaCl can promote the formation of Cl-AFt and play a good long-term stabilizing role. When the content of the alkali activator is 10% and the modulus is 1.0, the contents of CaO and NaCl are 10 and 1%, respectively. The BCM has the best efficiency in terms of UCS and As solidification. The UCS at 28 days was 5.4 MPa, and the leaching concentration of As was 0.309 mg/L, and the As solidification efficiency was up to 99.9%. In the improved BCR test, the proportions of residual and oxidizable states of arsenic increased by 19.6 and 13.5%, respectively, and the stability of heavy metals improved. These findings show that the BCM has good long-term stability and safety. Overall, this study shows that CaO and NaCl significantly increase the output of AFt and achieve the purpose of efficient and stable solidification of As by the BCM.