Long-term pilot study on advanced treatment of lake water by ultrafiltration / nanofiltration

Abstract

Advanced water treatment technologies, including ozone biologically activated carbon adsorption (O3-BAC), ultrafiltration (UF), and nanofiltration (NF), are essential for enhancing drinking water quality. O3-BAC and UF excel in pathogen, virus, and by-product removal, while NF promises enhanced contaminant elimination for high-quality water. However, the implementation of combined UF/NF dual-membrane treatment processes in large-scale water treatment facilities using surface water sources like lakes remains relatively novel. The lack of long-term operational data is the main reason for the limited widespread adoption. To address this, two pilot systems were established: one comprising ‘O3-BAC + pressure-driven UF(I) + NF(I) (Route 1 at 6.4m3/h)’, and the other ‘immersed UF(II) + NF(II) (Route 2 at 3.2m3/h)’, undergoing a year-long evaluation. The trials showed that the dual-membrane systems were effective and resistant to interference. Notably, they achieved removal efficiencies exceeding 98 % for turbidity, UV254 absorbance, fluorescence substances, and algae, alongside significant reductions in odor (80 %) and total dissolved solids (TDS) by 30 %. Both membrane systems display promising performance and O3-BAC is recommended as a pretreatment process. Analysis revealed that the primary constituents of membrane fouling on the NF membranes are aluminum silicate, SiO2, CaCO3 particles, and organic pollutants, which are typically formed through interactions between calcium ions and dissolved organic matter (DOM). The most effective cleaning protocol involves acidic-alkaline treatments. This study provides valuable operational insights into advanced treatment processes using dual-membrane combinations for water treatment plants that rely on lake water sources.