Abstract

A long-range potential of B1(3∑+) state of the mercury–argon molecules was derived using a LeRoy–Bernstein procedure. The procedure was applied to B1(3∑+)←X0(1∑+) excitation spectrum that was recorded previously. A dissociation energy, an effective vibrational index at the dissociation limit, and an asymptotic behavior of the B1(3∑+) state potential energy curve were determined. The result was compared with others available in the literature showing versatility of the method.

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