Abstract
AbstractThe effects of the substituent X on the homolysis rate constants (kd) of SG1‐propionate type alkoxyamines (SG1‐CHMeCOOX) are analyzed by a multiparametric equation with υ, the steric constant and σI, the polar inductive/field Hammett constant of X. An influence of long‐range polar and steric effects on kd was observed, that is, decrease in kd with increasing size of the X group and increase in kd with increasing polarity of the X group. Copyright © 2006 John Wiley & Sons, Ltd.
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