Abstract
Long-lived 9-cyano-9,10-dimethylphenanthrenyl cation was generated in superacidic medium, and its structure was determined by 1H and 13C NMR spectroscopy. The energy barrier to 1,2-shift of the cyano group in 9-cyano-9,10-dimethylphenanthrenyl cation was estimated by NMR and DFT calculations.
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