Locally Derived, Meteoric Fluid Infiltration Was Responsible for Widespread Late Paleozoic Illite Authigenesis in the Appalachian Basin

Abstract

AbstractIsotopic and geochronologic investigation of authigenic, K‐bearing clays in the Appalachian Plateau of the northeastern U.S. Midcontinent yields new insights about the tectonic and diagenetic history of the North American sedimentary cover sequence. In situ texture analysis by High Resolution X‐ray Texture Goniometry indicates preservation of bedding‐parallel diagenetic fabrics with burial depths of 2–5 km, and illite mineralization temperatures are spatially variable, ranging from 80 to 190 °C, correlating to similar depths of 3–6 km. The mineralizing geofluid is surface derived, with δD values ranging from −48‰ to −72‰ (in the range of predicted Pangea meteoric fluid). In addition, we find that mineralizing fluid δD values increase away from the orogenic front, consistent with a rain shadow effect from the high elevation Appalachian orogen. The age of authigenic illite is constrained by 40Ar/39Ar geochronology to 308–318 Ma, reflecting Upper Carboniferous diagenesis. We postulate that far‐field stress transmission from continent‐continent collision created regional permeability pathways for surface fluids, altering the hydrologic architecture of the brittle crust and allowing meteoric fluid infiltration into upper crustal rocks. This interpretation challenges the popular view of tectonically forced, lateral fluid flow from the Appalachian orogen (squeegee hypothesis).