Abstract
Anionic Doping In article number 2109694, Hong Yu, Cheng-Feng Du, Xing-Long Wu, and co-workers develop Cl-doped Na3V2(PO4)2O2F (NVPO2−xClxF) as superior cathode material for sodium-ion batteries. In NVPO2−xClxF, Cl doping tunes the electronic structure and causes the electron redistribution on vanadium center/dangling anions. As a result, a revised redox behavior of vanadium and increased Na+- diffusivity/electrochemical properties are achieved.
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