Abstract

Few organic compounds of selenium are known and, consequently, very little published data are available concerning the various vibrations around the selenium atom. The present paper discusses the C=Se vibration in selenosemicarbazones by comparing their infrared spectra with those of corresponding Se-benzyl derivatives in which the C=Se group has been replaced by a C—Se—Bz. On this basis, it can be seen that a band at 800–780 cm−1 in the spectra of selenosemicarbazones is absent in the spectra of the benzyl derivatives. This band is assigned to the C=Se vibration.

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