Abstract
AbstractThe local order in liquid bromobenzene is studied by measurement of the extended X‐ray absorption fine structure (EXAFS) of bromine. Following standard procedures for data reduction and data interpretation the deduced intramolecular distances are in very good agreement with other spectroscopic methods. From the remaining intermolecular distances a configuration of maximum occurrence probability can be constructed, which is caused by strongly attractive interaction of the bromine atom with other bromine atoms as well as with the aromatic system. The combination of these results with X‐ray and neutron diffraction data gives a detailed picture of the local order, consistent with the three different techniques applied in this work.
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