Local Nodal Cooper Pairs in Multiorbital Systems

Abstract

We show the emergence of a new class of superconductivity in multiorbital systems, focusing on non-Kramers f$^2$ states. The Cooper pairs in this class of superconductivity mainly consist of local pairs with the same symmetry as the local f$^2$ ground states. When the local ground state is an anisotropic representation, the superconducting gap has nodes on the Fermi surface. This nodal superconductivity is mediated by the strong onsite inter-orbital attractions as a consequence of negative-$U$ physics generalized to multiorbital systems. We show that this is indeed realized in a simple two-orbital model with antiferro Hund's coupling and enhanced inter-orbital interaction derived via a systematic local down folding. Finally, we briefly discuss superconductivity in Pr-1-2-20 compounds, UBe$_{13}$, and PrOs$_4$Sb$_{12}$ in view of the present mechanism.