Abstract

In this work, the synergy effects of the stress generation and temperature rise of slurry on the local corrosion during Cu CMP. We observed that the magnitude of generated stress was proportionate to the formation rate of Cu oxide. When specific additive was added into H2O2 solution, re-crystallization, which occurred to minimize the generated stress on the film, caused the breakdown of Cu oxide. The increase in Cu etch rate was resulted from an increased slurry temperature. Therefore, severe local corrosion, particularly at the recess area, occurred through the breakdown of Cu oxide and the temperature rise of slurry.

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