Abstract

The local (or polyhedron) compressibility of the Cr3+ -centered octahedron in spinal crystal is studied from the pressure-induced R-line shift. The result suggests that the local compressibility is about 0.6 of the compressibility of the host spinel crystal. This local compressibility is also consistent with that obtained from the pressure-induced shift of the 4T2 band and can be regarded as reasonable.

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