Abstract

The diverse local environment of zinc ions in a ZnCl2 solution, depending on the symmetry, ligand type, and solution concentration, has been analyzed using the data in the literature. Experimental zinc K-edge XANES spectra in a ZnCl2 aqueous solution with a critically low concentration (10–3 М) have been theoretically analyzed. It is shown that Zn(H2O) complexes with Zn2+ ions in the octahedral coordination environment of water molecules are dominant in this solution.

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