Abstract
We investigate the physical origins of the surface nonlinear susceptibility responsible for surface optical second-harmonic generation. Experiments performed on simple covalent systems were designed to distinguish between the nonlocal electric-quadrupole-type nonlinearity induced by field discontinuity and the local intrinsic, electric-dipole-type nonlinearity of a surface or interface. We find that both mechanisms could operate: The latter usually dominates when the surface layer has a strong structural asymmetry with the fundamental or the second-harmonic frequency at resonance with a dipole-allowed transition.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
