Loading rate and temperature dependence of flexural behavior in injection-molded glass fiber reinforced polypropylene composites

Abstract

This paper is concerned with the influence of loading rate/temperature and frequency/temperature on static flexural behavior and dynamic mechanical properties of injection molded glass fiber reinforced polypropylene (GFPP) composites, respectively. Furthermore, the mechanism of long-term durability of PP and GFPP was investigated by the master curve of storage modulus constructed based on the Time-Temperature-Superposition (TTSP) method. Three-point bending tests at various loading rates/temperatures and dynamic mechanical analysis (DMA) at various frequencies/temperatures are performed. The time-temperature dependence of static flexural properties (modulus, E, and strength, σ) and dynamic properties (storage modulus, E’) in PP and GFPP is discussed. The results show that both static flexural behavior and dynamic mechanical behavior of PP and GFPP have significant time-temperature dependent phenomenon, which conforms to the time-temperature equivalence principle. The long-term durability of GFPP depends on the matrix resin rather than the GF reinforcement and its interface at temperatures above the glass transition temperature (Tg).