Abstract
Polyarylether dendrons as macroinitiators for the “living”/controlled free radical copolymerization of N-phenylmaleimide (PhMI) and styrene (St) have been demonstrated. The copolymerization was carried out in bulk or anisole with CuBr/bipy catalyst at 100—130℃. It is found that the resulting copolymers possess predetermined molecular weights and narrower polydispersities (1.18 M w / M n r PhMI = 0.0207, and r St = 0.0484, respectively.
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