Abstract

A novel, highly soluble and solution processable Fe(II) spin cross-over (SCO) coordination polymer shows an SCO temperature at T1/2 ∼ 302 K. Bottom-up self-assembly of this supramolecular polymer in THF–water formed a several micron long nano-tape network. Further solution processing using a lithographically controlled wetting technique produced aligned 1D arrays of SCO nano-tape bundles.

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